The addition of nitrile oxides to C-60

被引：55

作者：

Meier, MS ^{[1
]}

Poplawska, M ^{[1
]}

机构：

[1] TECH UNIV WARSAW,FAC CHEM,POLITECH,PL-00664 WARSAW,POLAND

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4020(96)00112-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,3-dipolar cycloaddition of nitrile oxides to C-60 is described. These reactions result in the formation of fullerene-fused isoxazdine heterocycles bearing a series of different substituents in 3-position. The preparation and spectroscopic characterization of these compounds are reported, as well as some investigations of the reactivity of these heterocycles. It is found that fullerene isoxazolines are less reactive than aliphatic isoxazolines. (C) 1996 Elsevier Science Ltd

引用

页码：5043 / 5052

页数：10