A reexamination of the structure of "Honeycomb cadmium cyanide"

被引：9

作者：

Abrahams, BF ^{[1
]}

Hoskins, BF ^{[1
]}

Lam, YH ^{[1
]}

Robson, R ^{[1
]}

Separovic, F ^{[1
]}

Woodberry, P ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2001年 / 156卷 / 01期

关键词：

D O I：

10.1006/jssc.2000.8957

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The low-temperature crystal structure of Cd(CN), 2/3H(2)O .t-BuOH (230 K) is reported, Pbcm, a = 8,694(1), b = 16,908(4), c = 21.157(3) Angstrom. Although the cell has approximately twice the volume of the previously reported room temperature cell the 3D cadmium-cyanide framework has essentially the same connectivity. The hydrogen bonded t-BuOH/H2O system is much better defined at low temperature and this new insight together with solid-state NMR data afford an improved model of the room temperature structure, which is now reported in the space group Cmmm. (C) 2001 Academic Press.

引用

页码：51 / 56

页数：6

共 14 条

[1] A HONEYCOMB FORM OF CADMIUM CYANIDE - A NEW TYPE OF 3-D ARRANGEMENT OF INTERCONNECTED RODS GENERATING INFINITE LINEAR CHANNELS OF LARGE HEXAGONAL CROSS-SECTION
ABRAHAMS, BF
HOSKINS, BF
ROBSON, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) : 60 - 61
[2] THE ARCHETYPE FOR A NEW CLASS OF SIMPLE EXTENDED 3D HONEYCOMB FRAMEWORKS - THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF CD(CN)5/3(OH)1/3.1/3(C6H12N4), CD(CN)2.1/3(C6H12N4), AND CD(CN)2.2/3H2O.TBUOH (C6H12N4 = HEXAMETHYLENETETRAMINE) REVEALING 2 TOPOLOGICALLY EQUIVALENT BUT GEOMETRICALLY DIFFERENT FRAMEWORKS
ABRAHAMS, BF
HOSKINS, BF
LIU, JP
ROBSON, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) : 3045 - 3051
[3] TOPOLOGICAL REARRANGEMENT WITHIN A SINGLE-CRYSTAL FROM A HONEYCOMB [CD(CN)2]N3D NET TO A DIAMOND NET
ABRAHAMS, BF
HARDIE, MJ
HOSKINS, BF
ROBSON, R
WILLIAMS, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) : 10641 - 10643
[4] TEMPERATURE-DEPENDENCE OF PB-207 MAS SPECTRA OF SOLID LEAD NITRATE - AN ACCURATE, SENSITIVE THERMOMETER FOR VARIABLE-TEMPERATURE MAS
BIELECKI, A
BURUM, DP
[J]. JOURNAL OF MAGNETIC RESONANCE SERIES A, 1995, 116 (02) : 215 - 220
[5] Mineralomimetic chemistry as a modern aspect of co-ordination chemistry
Iwamoto, T
Nishikiori, S
Kitazawa, T
Yuge, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22): : 4127 - 4136
[6] GUEST-DEPENDENT [CD(CN)2]N HOST STRUCTURES OF CADMIUM CYANIDE ALCOHOL CLATHRATES - 2 NEW [CD(CN)2]N FRAMEWORKS FORMED WITH PRNOH AND PRIOH GUESTS
KIM, J
WHANG, D
LEE, JI
KIM, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) : 1400 - 1402
[7] NOVEL CLATHRATE COMPOUND OF CADMIUM CYANIDE HOST WITH AN ADAMANTANE-LIKE CAVITY - CADMIUM CYANIDE-CARBON TETRACHLORIDE (1/1)
KITAZAWA, T
NISHIKIORI, S
KURODA, R
IWAMOTO, T
[J]. CHEMISTRY LETTERS, 1988, (10) : 1729 - 1732
[8] KITAZAWA T, 1989, J CHEM SOC CHEM COMM, P891
[9] Some thoughts on choosing the correct space group
Marsh, RE
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1995, 51 : 897 - 907
[10] FRAMEWORK ORDERING IN SOLID CADMIUM CYANIDES FROM CD-113 NMR-SPECTROSCOPY
NISHIKIORI, S
RATCLIFFE, CI
RIPMEESTER, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (10) : 735 - 736

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