Silica-bound copper(II) triazacyclononane: a robust material for the heterogeneous hydrolysis of a phosphodiester

被引：42

作者：

Bodsgard, BR ^{[1
]}

Burstyn, JN ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 07期

关键词：

D O I：

10.1039/b005264g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) triazacyclononane, a catalyst for the hydrolysis of phosphate esters, has been covalently immobilized onto a silica surface and the resulting compound is a robust material that can effect heterogeneous phosphodiester hydrolysis.

引用

页码：647 / 648

页数：2

共 14 条

[1] DEVELOPING ARTIFICIAL HYDROLYTIC METALLOENZYMES BY A UNIFIED MECHANISTIC APPROACH [J].

CHIN, J .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (05) :145-152

[2] A NEW APPROACH FOR THE PREPARATION OF A HYDRIDE-MODIFIED SUBSTRATE USED AS AN INTERMEDIATE IN THE SYNTHESIS OF SURFACE-BONDED MATERIALS [J].

CHU, CH ;

JONSSON, E ;

AUVINEN, M ;

PESEK, JJ ;

SANDOVAL, JE .

ANALYTICAL CHEMISTRY, 1993, 65 (06) :808-816

[3] FACTORS AFFECTING CHELATION OF CARBOXYLATES TO CIS-DIAQUA CO(III) COMPLEXES - IMPLICATIONS ON THE REACTIVITY OF THE METAL-COMPLEXES FOR HYDROLYZING ESTERS, AMIDES, NITRILES, AND PHOSPHATES [J].

CONNOLLY, JA ;

KIM, JH ;

BANASZCZYK, M ;

DROUIN, M ;

CHIN, J .

INORGANIC CHEMISTRY, 1995, 34 (05) :1094-1099

[4] Mechanistic studies of dichloro(1,4,7-triazacyclononane)copper(II)-catalyzed phosphate diester hydrolysis [J].

Deal, KA ;

Burstyn, JN .

INORGANIC CHEMISTRY, 1996, 35 (10) :2792-2798

[5] AN OXYGEN-NITROGEN DONOR MACROCYCLE IMMOBILIZED ON SILICA-GEL - A REAGENT SHOWING HIGH SELECTIVITY FOR COPPER(II) IN THE PRESENCE OF COBALT(II), NICKEL(II), ZINC(II) OR CADMIUM(II) [J].

DUDLER, V ;

LINDOY, LF ;

SALLIN, D ;

SCHLAEPFER, CW .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (09) :1557-1563

[6] Macrocycles with a single pendant arm: Synthesis of N-R-(1,4,7-triazacyclononane) [L,R=4-but-1-ene; L'=3-prop-1-ene]: Synthesis of the Cu-I complex [CuL]I and synthesis and crystals structure of the Cu-II complex [CuL(2)][BPh(4)]2 and the mu-hydroxy bridged Cu-II dimer [LCu(mu-OH)(2)CuL][BPh(4)](2) [J].

Farrugia, LJ ;

Lovatt, PA ;

Peacock, RD .

INORGANICA CHIMICA ACTA, 1996, 246 (1-2) :343-348

[7] New silica-gel-bound polyazacycloalkanes and characterization of their copper(II) complexes using electron spin resonance spectroscopy [J].

Gros, C ;

Rabiet, F ;

Denat, F ;

Brandes, S ;

Chollet, H ;

Guilard, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (07) :1209-1214

[8] Synthesis, reactions and structure of a hydroxo-bridged dinuclear Zn(II) complex: Modeling the hydrolytic zinc enzymes [J].

Gultneh, Y ;

Allwar ;

Ahvazi, B ;

Blaise, D ;

Butcher, RJ ;

Jasinski, J ;

Jasinski, J .

INORGANICA CHIMICA ACTA, 1996, 241 (02) :31-38

[9] HYDROLYSIS OF UNACTIVATED PEPTIDE-BONDS BY A MACROCYCLIC COPPER(II) COMPLEX - CU([9]ANEN(3))CL-2 HYDROLYZES BOTH DIPEPTIDES AND PROTEINS [J].

HEGG, EL ;

BURSTYN, JN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (26) :7015-7016

[10] A (-) menthyl bonded silica phase for chiral separations: Synthesis and solid state NMR characterization [J].

Lynch, B ;

Glennon, JD ;

Troltzsch, C ;

Menyes, U ;

Pursch, M ;

Albert, K .

ANALYTICAL CHEMISTRY, 1997, 69 (09) :1756-1762

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