Direct decomposition of NO over BaO/Y2O3 catalyst

NO direct decomposition on BaO/Y2O3 oxide catalyst was investigated and it was found that BaO supported on Y2O3 or Sc2O3 is highly active to NO decomposition into N-2. The highest N-2 yield of ca.90% at 1123K was achieved at 5 mol% BaO supported on Y2O3. On this catalyst, NO conversion decreases with increasing oxygen partial pressure, P-02, however reasonably high N-2 yield (ca.40%) was exhibited under co-feeding of 5% O-2 and P-02 dependence is as small as -0.23. From NO-TPD results, large desorption peak of oxygen was observed around 773K suggesting that weak adsorption strength of O-2 on BaO/Y2O3 catalyst. In case of NO, large NO desorption peak was also observed around 473K and so NO adsorption was improved by loading BaO on Y2O3. In addition, part of NO desorbs as O-2 and NO, and small amount of N-2 desorbs at 773 K. This suggests that disproportional reaction of NO (3NO = N-2 + NO3ad or NO = N2Oad + NO2ad) occurred and the surface of the catalyst was covered with nitrogen oxide species. In spite of small surface area of BaO/Y2O3 (1.1m(2)/g), reasonably high N-2 yield (ca.30%) is shown at a high space velocity of 40,000h(-1). (C) 2011 Elsevier B. V. All rights reserved.