The atom transfer radical polymerization of lauryl acrylate

被引：46

作者：

Beers, KL ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15217 USA

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 2001年 / 38卷 / 07期

基金：

美国安德鲁·梅隆基金会;

关键词：

controlled/living radical polymerization; atom transfer radical polymerization; ATRP; ligands; lauryl acrylate;

D O I：

10.1081/MA-100103876

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The atom transfer radical polymerization (ATRP) of dodecyl (or lauryl) acrylate (LA) has been studied and optimized to yield polymers with predetermined molecular weights and low polydispersities. The poor solubility of the catalyst complex formed with linear tridentate amines and Cu(I)Br in both LA and the non-polar solvents required for the formed poly(lauryl acrylate) (pLA) resulted in poor control of the polymer molecular weights and high polydispersity. The use of a soluble catalyst formed by complexing copper with 4,4'-di(5-nonyl)-2,2'-bipyridine, improved both molecular weight control and polydispersities. The experimental conditions were further optimized by adding deactivating Cu(II) complex to the initial reaction mixture to compensate qualitatively for differences in the rate of termination relative to other acrylates.

引用

页码：731 / 739

页数：9

共 35 条

[11] Controlled/''living'' radical polymerization. Kinetics of the homogeneous atom transfer radical polymerization of styrene [J].

Matyjaszewski, K ;

Patten, TE ;

Xia, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (04) :674-680

[12] An investigation into the CuX/2,2′-bipyridine (X = Br or Cl) mediated atom transfer radical polymerization of acrylonitrile [J].

Matyjaszewski, K ;

Jo, SM ;

Paik, HJ ;

Shipp, DA .

MACROMOLECULES, 1999, 32 (20) :6431-6438

[13] Synthesis and characterization of star polymers with varying arm number, length, and composition from organic and hybrid inorganic/organic multifunctional initiators [J].

Matyjaszewski, K ;

Miller, PJ ;

Pyun, J ;

Kickelbick, G ;

Diamanti, S .

MACROMOLECULES, 1999, 32 (20) :6526-6535

[14]

Matyjaszewski K, 1999, CHEM-EUR J, V5, P3095, DOI 10.1002/(SICI)1521-3765(19991105)5:11<3095::AID-CHEM3095>3.0.CO

[15]

2-#

[16] Controlled/"living" atom transfer radical polymerization of methyl methacrylate using various initiation systems [J].

Matyjaszewski, K ;

Wang, JL ;

Grimaud, T ;

Shipp, DA .

MACROMOLECULES, 1998, 31 (05) :1527-1534

[17]

MATYJASZEWSKI K, 1998, CONTROLLED RADICAL P, V685

[18]

Matyjaszewski K., 2000, Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT, DOI DOI 10.1021/BK-2000-0768.FW001

[19]

MINODA M, 1999, AM CHEM SOC DIV POLY, V40, P399

[20] Polymers with very low polydispersities from atom transfer radical polymerization [J].

Patten, TE ;

Xia, JH ;

Abernathy, T ;

Matyjaszewski, K .

SCIENCE, 1996, 272 (5263) :866-868

← 1 2 3 4 →