Baeyer-Villiger-oxidation of cyclopentanone with aqueous hydrogen peroxide by acid heterogeneous catalysis

被引：104

作者：

Fischer, J ^{[1
]}

Hölderich, WF ^{[1
]}

机构：

[1] Aachen Tech Univ, Rhein Westfal TH Aachen, Dept Chem Technol & Heterogeneous Catalysis, D-52074 Aachen, Germany

来源：

APPLIED CATALYSIS A-GENERAL | 1999年 / 180卷 / 1-2期

关键词：

cyclopentanone; heterogeneous catalysis; aqueous hydrogen peroxide; ion exchange resin; solid acid;

D O I：

10.1016/S0926-860X(98)00378-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using aqueous hydrogen peroxide containing 30% H2O2, solid acid catalysts were compared in their performance as catalysts for the transformation of cyclopentanone to delta-valerolactone. It could be shown that organic ion exchange resins with sulphonic acid groups providing acid functionality are promising catalysts for this reaction. The variation of several reaction parameters was studied in more detail. The obtained results were compared to investigations of zeolites and Nafion(R) composite materials. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：435 / 443

页数：9

共 11 条

[1]

BAEYER A, 1999, BER, V32, P3619

[2] OPTICALLY-ACTIVE LACTONES FROM A BAEYER-VILLIGER-TYPE METAL-CATALYZED OXIDATION WITH MOLECULAR-OXYGEN [J].