Surface-initiated atom transfer radical polymerization from halogen-terminated Si(111) (Si-X, X = Cl, Br) surfaces for the preparation of well-defined polymer-Si hybrids

被引：49

作者：

Xu, FJ ^{[1
]}

Cai, QJ ^{[1
]}

Kang, ET ^{[1
]}

Neoh, KG ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore

来源：

LANGMUIR | 2005年 / 21卷 / 08期

关键词：

D O I：

10.1021/la0473714

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The halogen-terminated Si(111) (Si-X, X = Cl, Br) surfaces contain effective initiators for surface-initiated atom transfer radical polymerization. Well-defined polymer-Si hybrids, consisting of covalently tethered (Si-C bonded) functional polymer brushes, can be prepared directly from the Si-X surfaces.

引用

页码：3221 / 3225

页数：5

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