Quantitative measures of solvent polarity

被引：363

作者：

Katritzky, AR ^{[1
]}

Fara, DC

Yang, HF

Tämm, K

Tamm, T

Karelson, M

机构：

[1] Univ Florida, Dept Chem, Ctr Heterocycl, Gainesville, FL 32611 USA

[2] Univ Tartu, Dept Chem, EE-51014 Tartu, Estonia

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 01期

关键词：

D O I：

10.1021/cr020750m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The quantative scales and models, to describe the solvent polarity on chemical reactivity and physical properties of compounds, in condensed media were developed. The different individual solvent scales, based on empirical parameters were developed using pure solvents. Different alternatives were proposed to measure solute-solvent interactions, resulting in a large variety of 'solvent polarity scales' based on diverse solvent-sensitive reference processes/empirical parameters. The multiparameter approaches to explain solvent effects on chemical and physical properties were proposed. The position and potential for the development of solvent polarity were also presented.

引用

页码：175 / 198

页数：24

共 242 条

[1] REGARDING A GENERALIZED SCALE OF SOLVENT POLARITIES [J].

ABBOUD, JL ;

TAFT, RW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (25) :8325-8327

[2] Critical compilation of scales of solvent parameters. Part I. Pure, non-hydrogen bond donor solvents - Technical report [J].

Abboud, JLM ;

Notario, R .

PURE AND APPLIED CHEMISTRY, 1999, 71 (04) :645-718

[3] INTERPRETATION OF A GENERAL SCALE OF SOLVENT POLARITIES - SIMPLIFIED REACTION FIELD-THEORY MODIFICATION [J].

ABBOUD, JLM ;

TAFT, RW .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (03) :412-419

[4]

ABBOUD JLM, 1981, PROG PHYS ORG CHEM, V13, P485

[5] FLUORESCENCE PROPERTIES AND EXCITED-STATE INTERACTIONS OF 7-HYDROXY-4-METHYLCOUMARIN LASER-DYE [J].

ABDELMOTTALEB, MSA ;

ELSAYED, BA ;

ABOALY, MM ;

ELKADY, MY .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1989, 46 (03) :379-390

[6] IMPROVEMENTS OF THE EMPIRICAL PISTAR SOLVENT POLARITY SCALE [J].

ABE, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (08) :2328-2338

[7]

Abraham M.H., 1987, J CHEM SOC P2, V7, P913

[8] HYDROGEN-BONDING .4. AN ANALYSIS OF SOLUTE HYDROGEN-BOND BASICITY, IN TERMS OF COMPLEXATION CONSTANTS (LOG-K), USING F1 AND F2 FACTORS, THE PRINCIPAL COMPONENTS OF DIFFERENT KINDS OF BASICITY .3. [J].

ABRAHAM, MH ;

GRELLIER, PL ;

PRIOR, DV ;

MORRIS, JJ ;

TAYLOR, PJ ;

MARIA, PC ;

GAL, JF .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1989, 2 (03) :243-254

[9] HYDROGEN-BONDING .8. POSSIBLE EQUIVALENCE OF SOLUTE AND SOLVENT SCALES OF HYDROGEN-BOND BASICITY OF NON-ASSOCIATED COMPOUNDS [J].

ABRAHAM, MH ;

BUIST, GJ ;

GRELLIER, PL ;

MCGILL, RA ;

PRIOR, D ;

OLIVER, S ;

TURNER, E ;

MORRIS, JJ ;

TAYLOR, PJ ;

NICOLET, P ;

MARIA, PC ;

GAL, JF ;

ABBOUD, JLM ;

DOHERTY, RM ;

KAMLET, MJ ;

SHUELY, WJ ;

TAFT, RW .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1989, 2 (07) :540-552

[10] HYDROGEN-BONDING .31. CONSTRUCTION OF A SCALE OF SOLUTE EFFECTIVE OR SUMMATION HYDROGEN-BOND BASICITY [J].

ABRAHAM, MH .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (12) :660-684

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