Quantitative measures of solvent polarity

被引:373
作者
Katritzky, AR [1 ]
Fara, DC
Yang, HF
Tämm, K
Tamm, T
Karelson, M
机构
[1] Univ Florida, Dept Chem, Ctr Heterocycl, Gainesville, FL 32611 USA
[2] Univ Tartu, Dept Chem, EE-51014 Tartu, Estonia
关键词
D O I
10.1021/cr020750m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The quantative scales and models, to describe the solvent polarity on chemical reactivity and physical properties of compounds, in condensed media were developed. The different individual solvent scales, based on empirical parameters were developed using pure solvents. Different alternatives were proposed to measure solute-solvent interactions, resulting in a large variety of 'solvent polarity scales' based on diverse solvent-sensitive reference processes/empirical parameters. The multiparameter approaches to explain solvent effects on chemical and physical properties were proposed. The position and potential for the development of solvent polarity were also presented.
引用
收藏
页码:175 / 198
页数:24
相关论文
共 242 条
[61]   Correlation between solvation of peptide-resins and solvent properties [J].
Cilli, EM ;
Oliveira, E ;
Marchetto, R ;
Nakaie, CR .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (25) :8992-9000
[62]   REVERSED-PHASE LIQUID-SOLID CHROMATOGRAPHY ON MODIFIED CARBON-BLACK [J].
COLIN, H ;
EON, C ;
GUIOCHON, G .
JOURNAL OF CHROMATOGRAPHY, 1976, 122 (JUL7) :223-242
[63]   USE OF CALCULATED QUANTUM-CHEMICAL PROPERTIES AS SURROGATES FOR SOLVATOCHROMIC PARAMETERS IN STRUCTURE-ACTIVITY-RELATIONSHIPS [J].
CRAMER, CJ ;
FAMINI, GR ;
LOWREY, AH .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (11) :599-605
[64]   RESPONSE OF TRIFLATES TO SOLVENT IONIZING POWER - A Y OTF SCALE BASED ON 7-NORBORNYL TRIFLATE [J].
CREARY, X ;
MCDONALD, SR .
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (04) :474-479
[65]   INFRA-RED SOLVENT SHIFTS AND MOLECULAR INTERACTIONS .X. TRIATOMIC MOLECULES CS2 COS AND SO2 [J].
DAVID, JG ;
HALLAM, HE .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (03) :593-&
[66]  
DAVIS KMC, 1967, J CHEM SOC B, V11, P1128
[67]   PREDICTION OF INFINITE DILUTION ACTIVITY-COEFFICIENTS OF SULFUR-DIOXIDE IN ORGANIC-SOLVENTS [J].
DEMYANOVICH, RJ ;
LYNN, S .
JOURNAL OF SOLUTION CHEMISTRY, 1991, 20 (07) :693-701
[68]   NILE RED AS A SOLVATOCHROMIC DYE FOR MEASURING SOLVENT STRENGTH IN NORMAL LIQUIDS AND MIXTURES OF NORMAL LIQUIDS WITH SUPERCRITICAL AND NEAR CRITICAL FLUIDS [J].
DEYE, JF ;
BERGER, TA ;
ANDERSON, AG .
ANALYTICAL CHEMISTRY, 1990, 62 (06) :615-622
[69]  
DIMROTH K, 1963, LIEBIGS ANN CHEM, V661, P1
[70]   THE PY SCALE OF SOLVENT POLARITIES [J].
DONG, DC ;
WINNIK, MA .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (11) :2560-2565