[Ni(R2pipdt)2](BF4)2(R2pipdt=1,4-disubstituted-piperazine-3,2-dithione) as useful precursors of mixed-ligand dithiolenes of interest for non-linear optics

被引：67

作者：

Bigoli, F

Chen, CT

Wu, WC

Deplano, P ^{[1
]}

Mercuri, ML

Pellinghelli, MA

Pilia, L

Pintus, G

Serpe, A

Trogu, EF

机构：

[1] Univ Cagliari, Dipartimento Chim Inorgan & Analit, Cittadella Monserrato, I-09042 Cagliari, Italy

[2] CNR, Ctr Studio Strutturist Diffrattometr, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

[3] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b106064n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple method to obtain in high yields mixed-ligand nickel-dithiolene complexes, which show strong negative solvatochromism and negative first molecular hyperpolarizability, and the use of Raman spectroscopy to establish the extent of electronic delocalisation in these complexes, are reported.

引用

页码：2246 / 2247

页数：2

共 17 条

[11] THE SYNTHESIS OF DITHIOLENE DYES WITH STRONG NEAR-IR ABSORPTION [J].