Solid state coordination chemistry of the copper cyanide organoamine system:: hydrothermal synthesis and structural characterization of [{Cu2(bpy)2(CN)}2Cu5(CN)7]•0.17H2O

被引：60

作者：

Chesnut, DJ ^{[1
]}

Kusnetzow, A ^{[1
]}

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a806500d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of CuCN, KCN, 2,2'-bipyridyl (bpy) and water yields [{Cu-2(bpy)(2)(CN)}(2)Cu-5(CN)(7)]. 0.17H(2)O 1, a two-dimensional copper-cyano network intercalated by [(bpy)(2)(Cu)(2)(CN)](+) cations and water of crystallization.

引用

页码：4081 / 4083

页数：3

共 16 条

[1] A new CuI(SCN) structural motif:: synthesis of an uncharged three-dimensional co-ordination network [J].

Blake, AJ ;

Champness, NR ;

Crew, M ;

Hanton, LR ;

Parsons, S ;

Schroder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (10) :1533-1534

[2] ADVANCED INORGANIC MATERIALS - AN OPEN HORIZON [J].

CHEETHAM, AK .

SCIENCE, 1994, 264 (5160) :794-795

[3] Solid state coordination chemistry of the copper cyanide organoamine system:: hydrothermal syntheses and structural characterization of [(Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)] [J].

Chesnut, DJ ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 1998, (16) :1707-1708

[4] Hydrothermal synthesis and structural characterization of [Cu(en)(2)](2)Cu7Cl11: A three-dimensional open-framework copper halide with occluded [Cu(en)(2)](2+) cations [J].

DeBord, JRD ;

Lu, YJ ;

Warren, CJ ;

Haushalter, RC ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 1997, (15) :1365-1366

[5] CHIMIE DOUCE APPROACHES TO THE SYNTHESIS OF METASTABLE OXIDE MATERIALS [J].

GOPALAKRISHNAN, J .

CHEMISTRY OF MATERIALS, 1995, 7 (07) :1265-1275

[6] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].

Hagrman, D ;

Zubieta, C ;

Rose, DJ ;

Zubieta, J ;

Haushalter, RC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876

[7] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES [J].

HAUSHALTER, RC ;

MUNDI, LA .

CHEMISTRY OF MATERIALS, 1992, 4 (01) :31-48

[8] Giant voids in the hydrothermally synthesized microporous square pyramidal tetrahedral framework vanadium phosphates [HN(CH2CH2)(3)NH]K-1.35[V5O9(PO4)(2)]center dot xH(2)O and Cs-3[V5O9(PO4)(2)]center dot xH(2)O [J].

Khan, MI ;

Meyer, LM ;

Haushalter, RC ;

Schweitzer, AL ;

Zubieta, J ;

Dye, JL .

CHEMISTRY OF MATERIALS, 1996, 8 (01) :43-53

[9] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

[10] Biomineralization: the form(id)able part of bioinorganic chemistry! [J].

Mann, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (21) :3953-3961

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