Structural and electrical properties of bis(ethylenedithio)tetrathiafulvalenium hydrogen fumarate(2/1):: a BEDT-TTF mixed-valency salt with a hydrogen-bonding organic anion

被引：13

作者：

Giffard, M

Riou, A

Mabon, G

Mercier, N

Molinié, P

Nguyen, TP

机构：

[1] Univ Angers, Lab Ingn Mol & Mat Organ, CNRS, UMR 6501, F-49045 Angers, France

[2] Univ Nantes, Inst Mat, CNRS, UMR 6510, F-44072 Nantes, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 04期

关键词：

D O I：

10.1039/a810002k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electro-oxidation of BEDT-TTF in the presence of tetrabutylammonium hydrogen fumarate affords the salt (BEDT-TTF)(2)[(E)-HO2C-CH = CH-CO2], in which the BEDT-TTF units adopt a beta-type packing and the organic anions form infinite chains by hydrogen-bonding; this salt is a semiconductor and its room-temperature conductivity is ca, 3 S cm(-1).

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页码：851 / 853

页数：3

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