Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation

被引：33

作者：

Chong, Hui ^{[1
]}

Lin, Hsing-An ^{[1
]}

Shen, Mo-Yuan ^{[2
]}

Liu, Ching-Yuan ^{[3
]}

Zhao, Haichao ^{[1
]}

Yu, Hsiao-hua ^{[1
,2
]}

机构：

[1] Respons Organ Mat Lab, Wako, Saitama 3510198, Japan

[2] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

[3] Natl Cent Univ, Dept Chem & Mat Engn, Taoyuan 32001, Taiwan

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 13期

关键词：

ALTERNATING COPOLYMERS; EFFICIENT SYNTHESIS; COUPLING REACTIONS; FLUORESCENT-PROBE; DYES; POLYMERS; DERIVATIVES; THIOPHENE;

D O I：

10.1021/acs.orglett.5b00875

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-Catalyzed direct C-H arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) With 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 degrees C) provide moderate to good. yields (47%-72%) Of products having potential applications in fluorescent bioimaging and organic optoelectronics.

引用

收藏

页码：3198 / 3201

页数：4

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