Expanded ligands - An assembly principle for supramolecular chemistry

被引:217
作者
Constable, Edwin C. [1 ]
机构
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
关键词
supramolecular; 2,2 ': 6 ',2 ''-terpyridine; crystal engineering; coordination chemistry;
D O I
10.1016/j.ccr.2007.10.020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Expanded ligands incorporate metal-containing groups as spacers between metal-binding domains. This article presents the principle and analyses expanded ligands based upon {M(tpy)(2)}(tpy = 2,2':6',2 ''-terpyridine) scaffolds. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:842 / 855
页数:14
相关论文
共 109 条
[1]   Synthesis and pH-sensitive luminescence of bis-terpyridyl iridium(III) complexes incorporating pendent pyridyl groups [J].
Arm, KJ ;
Leslie, W ;
Williams, JAG .
INORGANICA CHIMICA ACTA, 2006, 359 (04) :1222-1232
[2]   Carbaborane-functionalised 2,2′:6′,2"-terpyridine ligands for metallosupramolecular chemistry:: Syntheses, complex formation, and the crystal and molecular structures of 4′-(optho-carboranyl)-2,2′:6′,2"-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2"-terpyridine [J].
Armspach, D ;
Constable, EC ;
Housecroft, CE ;
Neuburger, M ;
Zehnder, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :193-206
[3]   EFFECT OF TEMPERATURE ON THE PROTONATION CONSTANTS OF SOME AROMATIC, HETEROCYCLIC NITROGEN BASES AND THE ANION OF 8-HYDROXYQUINOLINE [J].
ASHTON, LA ;
BULLOCK, JI ;
SIMPSON, PWG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 :1961-1970
[4]   CRYSTAL STRUCTURE OF TEREPHTHALIC ACID [J].
BAILEY, M ;
BROWN, CJ .
ACTA CRYSTALLOGRAPHICA, 1967, 22 :387-&
[5]   New ruthenium bisterpyridinyl complexes, as efficient sensitizers of nanocrystalline, TiO2 films [J].
Beley, M ;
Bignozzi, CA ;
Kirsch, G ;
Alebbi, M ;
Raboin, JC .
INORGANICA CHIMICA ACTA, 2001, 318 (1-2) :197-200
[6]   Comparison of the photophysical properties of osmium(II) bis(2,2′:6′,2"-terpyridine) and the corresponding ethynylated derivative [J].
Benniston, AC ;
Harriman, A ;
Li, PY ;
Sams, CA .
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (10) :2302-2309
[7]  
BEVES JE, IN PRESS DALTON T
[8]   The conjugate acid of bis{4'-(4-pyridyl)-2,2': 6',2"-terpyridine} iron(II) as a self-complementary hydrogen-bonded building block [J].
Beves, Jonathon E. ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Kepert, Cameron J. ;
Neuburger, Markus ;
Price, David J. ;
Schaffner, Silvia .
CRYSTENGCOMM, 2007, 9 (11) :1073-1077
[9]   A palladium(II) complex of 4′-(4-pyridyl)-2,2′:6′,2"-terpyridine:: Lattice control through an interplay of stacking and hydrogen bonding effects [J].
Beves, Jonathon E. ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Neuburger, Markus ;
Schaffner, Silvia .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (10) :1185-1188
[10]   [n+n]-Heterometallomacrocyclic complexes (n ≥ 2) prepared from platinum(II)-centred ditopic 2,2′:6′,2"-terpyridine ligands:: dimensional cataloguing by pulsed-field gradient spin-echo NMR spectroscopy [J].
Beves, Jonathon E. ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Neuburger, Markus ;
Schaffner, Silvia ;
Shardlow, Ellen J. .
DALTON TRANSACTIONS, 2007, (16) :1593-1602