A palladium(II) complex of 4′-(4-pyridyl)-2,2′:6′,2"-terpyridine:: Lattice control through an interplay of stacking and hydrogen bonding effects

被引：25

作者：

Beves, Jonathon E. ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 10期

关键词：

Palladium(II); x-ray; 2,2 ': 6 ',2 ''-terpyridine; hydrogen bonding;

D O I：

10.1016/j.inoche.2007.07.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Pd(1)Cl]Cl where 1 = 4'-(4-pyridyl)-2,2':6',2 ''-terpyridine is reported. The single crystal structure of [Pd(1)Cl]Cl center dot 3H(2)O center dot DMF features rows of columns of [Pd(1)Cl](+) cations which are supported by Pd...Pd interactions (3.367(1) and 3.440(1) angstrom) and separated by hydrogen-bonded 4.8(2) nets of water molecules and Cl- ions. (c) 2007 Elsevier B.V. All rights reserved.

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页码：1185 / 1188

页数：4

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