The solid-state structure of bis(4′-(4-pyridy1)-2,2′: 6′, 2"-terpyridine)ruthenium hexafluorophosphate nitrate -: An expanded 4,4′-bipyridine

被引：36

作者：

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

Schaper, Frank ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 06期

关键词：

ruthenium(II); X-ray; 2,2 ': 6 ',2 ''-terpyridine; synthesis;

D O I：

10.1016/j.inoche.2006.03.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient synthesis of the ligand 4'-(4-pyridyl)-2,2':6,2"-terpyridine (2) is presented and the preparation, spectroscopic and structural characterisation of [Ru(2)(2)][PF6][NO3] center dot DMSO containing the metallotecton [Ru(2)(2)](2+) is reported. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：616 / 619

页数：4

共 20 条

[1]

Aakeroy C.B., 2004, COMPREHENSIVE COORDI, V1, P679

[2] Efficient synthesis of pyridines via a sequential solventless aldol condensation and Michael addition [J].

Cave, GWV ;

Raston, CL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (24) :3258-3264

[3] Toward benign syntheses of pyridines involving sequential solvent free aldol and Michael addition reactions [J].

Cave, GWV ;

Raston, CL .

CHEMICAL COMMUNICATIONS, 2000, (22) :2199-2200

[4] LIGAND REACTIVITY IN POLYPYRIDINE COMPLEXES - THE DEUTERIATION OF THE BIS(2,2'-6',2''-TERPYRIDINE)RUTHENIUM(II) CATION [J].

CONSTABLE, EC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (12) :2687-2689

[5] Preparation and structural characterisation of bis(4′-(3-pyridyl)-2,2′:6′,2"-terpyridine)ruthenium(II) hexafluorophosphate [J].

Constable, EC ;

Housecroft, CE ;

Neuburger, M ;

Schaffner, S ;

Schaper, F .

INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (04) :433-436

[6] PENDANT-FUNCTIONALIZED LIGANDS FOR METALLOSUPRAMOLECULAR ASSEMBLIES - RUTHENIUM(II) AND OSMIUM(II) COMPLEXES OF 4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (09) :1409-1418

[7] Metal-directed assembly of a box-like structure [J].

Constable, EC ;

Schofield, E .

CHEMICAL COMMUNICATIONS, 1998, (03) :403-404

[8] Development of supramolecular structure through alkylation of pendant pyridyl functionality [J].

Constable, EC ;

Housecroft, CE ;

Neuburger, M ;

Phillips, D ;

Raithby, PR ;

Schofield, E ;

Sparr, E ;

Tocher, DA ;

Zehnder, M ;

Zimmermann, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (13) :2219-2228

[9] LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (20) :2947-2950

[10]

CONSTABLE EC, 2006, IN PRESS CHEM EUR J

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