Efficient asymmetric transfer hydrogenation of activated olefins catalyzed by ruthenium amido complexes

被引：59

作者：

Chen, YC

Xue, D

Deng, JG ^{[1
]}

Cui, X

Zhu, J

Jiang, YZ

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 07期

关键词：

activated olefins; asymmetric transfer hydrogenation; ruthenium amido complexes;

D O I：

10.1016/j.tetlet.2003.12.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric transfer hydrogenation of activated olefins with chiral ruthenium amido complexes (Noyori catalyst) using formic acid-triethylamine azeotrope as hydrogen source resulted in excellent yields and high enantioselectivities (up to 88.5%). (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1555 / 1558

页数：4

共 49 条

[1] Asymmetric conjugate reduction of α,β-unsaturated esters using a chiral phosphine-copper catalyst
Appella, DH
Moritani, Y
Shintani, R
Ferreira, EM
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (40) : 9473 - 9474
[2] EQUILIBRIUM ACIDITIES IN DIMETHYL-SULFOXIDE SOLUTION
BORDWELL, FG
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (12) : 456 - 463
[3] ENANTIOSELECTIVE CATALYSIS .66. ENANTIOSELECTIVE CATALYTIC TRANSFER HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH FORMATES CATALYZED BY NOVEL RUTHENIUM PHOSPHINE COMPLEXES
BROWN, JM
BRUNNER, H
LEITNER, W
ROSE, M
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (05) : 331 - 334
[4] ENANTIOSELECTIVE CATALYSIS .43. ENANTIOSELECTIVE CATALYTIC TRANSFER-HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH TRIETHYLAMMONIUM FORMATE
BRUNNER, H
LEITNER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (09) : 1180 - 1181
[5] BRUNNER H, 1989, SYNTHESIS-STUTTGART, P743
[6] Cabaret D., 1970, CHEM COMMUN, P1064
[7] Multiple dendritic catalysts for asymmetric transfer hydrogenation
Chen, YC
Wu, TF
Deng, JG
Liu, H
Cui, X
Zhu, J
Jiang, YZ
Choi, MCK
Chan, ASC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (15) : 5301 - 5306
[8] Chen YC, 2001, CHINESE J CHEM, V19, P807
[9] Dendritic catalysts for asymmetric transfer hydrogenation
Chen, YC
Wu, TF
Deng, JG
Liu, H
Jiang, YZ
Choib, MCK
Chan, ASC
[J]. CHEMICAL COMMUNICATIONS, 2001, (16) : 1488 - 1489
[10] Tandem conjugate reduction-aldol cyclization using Stryker's reagent
Chiu, P
Szeto, CP
Geng, Z
Cheng, KF
[J]. ORGANIC LETTERS, 2001, 3 (12) : 1901 - 1903

← 1 2 3 4 5 →