Statistical thermodynamics of methanol and ethanol adsorption in zeolite NaZSM5

被引：17

作者：

Boddenberg, B ^{[1
]}

Rakhmatkariev, GU ^{[1
]}

Greth, R ^{[1
]}

机构：

[1] ACAD SCI,INST CHEM,TASHKENT 700170,UZBEKISTAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 09期

关键词：

D O I：

10.1021/jp963111m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A statistical thermodynamic treatment of the adsorption of methanol and ethanol in zeolite NaZSM5 at 303 K is presented that reproduces well the adsorption isotherm and differential heat of adsorption data published by M. M. Dubinin, G. U. Rakhmatkariev, and A. A. Isirikyan (Izv. Akad. Nauk SSSR, Ser. Khim. 1989, 11, 2636). The pore filling proceeds via the formation of monomeric up to tetrameric alcohol/cation complexes located in the channel intersections. The equilibrium concentrations of these s-meric complexes (s = 1-4) as a function of the overall loading as well as the potential energies and energies of formation of the complexes are determined.

引用

页码：1634 / 1640

页数：7

共 21 条

[1]

AKHMEDOV KS, 1987, IAN SSSR KH, V8, P1717

[2] H-1 MAGIC-ANGLE-SPINNING NMR-STUDIES OF THE ADSORPTION OF ALCOHOLS ON MOLECULAR-SIEVE CATALYSTS [J].