A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

被引：250

作者：

Guillerm, Vincent ^{[3
]}

Gross, Silvia ^{[1
,2
]}

Serre, Christian ^{[3
]}

Devic, Thomas ^{[3
]}

Bauer, Matthias ^{[4
]}

Ferey, Gerard ^{[3
]}

机构：

[1] Univ Padua, CNR, ISTM, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] Univ Padua, INSTM, UdR Padova, I-35131 Padua, Italy

[3] Univ Versailles St Quentin, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

[4] Inst Phys Chem, D-70569 Stuttgart, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 05期

关键词：

ORGANIC HYBRID POLYMERS; METAL-OXIDE CLUSTERS; BUILDING-BLOCKS; OXO CLUSTERS; COORDINATION POLYMERS; RETICULAR SYNTHESIS; DESIGN; STABILITY;

D O I：

10.1039/b914919h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)(4)(OMc)(12) (OMc = CH2 = CH(CH3)COO) with dicarboxylic acids (trans, trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

引用

页码：767 / 769

页数：3

共 30 条

[11] Mono-, di-, and trimetallic methacrylate-substituted metal oxide clusters derived from hafnium butoxide [J].

Gross, S ;

Kickelbick, G ;

Puchberger, M ;

Schubert, U .

MONATSHEFTE FUR CHEMIE, 2003, 134 (08) :1053-1063

[12] Variations in capping the Zr6O4(OH)4 cluster core.: X-ray structure analyses of [Zr6(OH)4O4(OOC-CH=CH2)10]2(μ-OOC-CH=CH2)4 and Zr6(OH)4O4(OOCR)12(PrOH) (R = Ph, CMe = CH2) [J].

Kickelbick, G ;

Wiede, P ;

Schubert, U .

INORGANICA CHIMICA ACTA, 1999, 284 (01) :1-7

[13] Oxozirconium methacrylate clusters: Zr-6(OH)(4)O-4(OMc)(12) and Zr4O2(OMc)(12) (OMc = methacrylate) [J].

Kickelbick, G ;

Schubert, U .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (04) :473-477

[14] Formation of organically surface-modified metal oxo clusters from carboxylic acids and metal alkoxides: a mechanistic study [J].

Kickelbick, G ;

Feth, MP ;

Bertagnolli, H ;

Puchberger, M ;

Holzinger, D ;

Gross, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (20) :3892-3898

[15] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[16] Control of the ratio of functional and non-functional ligands in clusters of the type Zr6O4(OH)4(carboxylate)12 for their use as building blocks for inorganic-organic hybrid polymers [J].

Kogler, FR ;

Jupa, M ;

Puchberger, M ;

Schubert, U .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (21) :3133-3138

[17] Modular Synthesis of Functional Nanoscale Coordination Polymers [J].

Lin, Wenbin ;

Rieter, William J. ;

Taylor, Kathryn M. L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (04) :650-658

[18] The pervasive chemistry of metal-organic frameworks [J].

Long, Jeffrey R. ;

Yaghi, Omar M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1213-1214

[19] Photopatternable di-ureasil-zirconium oxocluster organic-inorganic hybrids as cost effective integrated optical substrates [J].

Oliveira, Daniela C. ;

Macedo, Andreia G. ;

Silva, Nuno J. O. ;

Molina, Celso ;

Ferreira, Rute A. S. ;

Andre, Paulo S. ;

Dahmouche, Karim ;

Bermudez, Veronica De Zea ;

Messaddeq, Younes ;

Ribeiro, Sidney J. L. ;

Carlos, Luis D. .

CHEMISTRY OF MATERIALS, 2008, 20 (11) :3696-3705

[20] Can the clusters Zr6O4(OH)4(OOCR)12 and [Zr6O4(OH)4(OOCR)12]2 be converted into each other? [J].

Puchberger, Michael ;

Kogler, Franz Rene ;

Jupa, Myhedin ;

Gross, Silvia ;

Fric, Helmut ;

Kickelbick, Guido ;

Schubert, Ulrich .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (16) :3283-3293

← 1 2 3 →