Synthesis of poly(ferrocenyldialkoxysilane) polymers and formation of gels by non-hydrolytic gelation methods

被引：14

作者：

Calleja, G ^{[1
]}

Carre, F ^{[1
]}

Cerveau, G ^{[1
]}

Corriu, RJP ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, URA 5637, F-34095 Montpellier, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1998年 / 1卷 / 04期

关键词：

1,1 '-ferrocenediyldialkoxysilanes; poly(ferrocenylsilanes); non-hydrolytic sol-gel condensation; cyclic voltammetry;

D O I：

10.1016/S1387-1609(98)80047-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of new 1,1 '-ferrocenediyldialkoxysilanes Fe(eta-C5H4)(2)Si(OR)(2) M1-M3, with R = tBu, CH2Ph, iPr, is described. The X-ray diffraction of a single crystal has been performed in the case of M1. Thermal ring opening polymerisation of M1-M3 yielded the corresponding poly(ferrocenylsilane) polymers P1-P3. These linear polymers are soluble in polar solvents and exhibit high molecular weights. M3 and P1 have been introduced in a silica matrix by non-hydrolytic condensation. The electrochemical properties of the obtained gels GM3 and GP1 have been studied. (C) Academie des Sciences/Elsevier, Paris.

引用

页码：285 / 291

页数：7

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