Synthesis and electrorheology of camphorsulfonic acid doped polyaniline suspensions

被引:79
作者
Jang, WH
Kim, JW
Choi, HJ [1 ]
Jhon, MS
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
关键词
camphorsulfonic acid; polyaniline; chemical oxidation polymerization electrorheological fluid; suspension;
D O I
10.1007/s003960100534
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Semiconducting camphor-sulfortic acid doped polyaniline (PANI-CSA) particles were synthesized by chemical oxidation polymerization, and their chemical structure and particle size were examined via Fourier transform IR spectroscopy and scanning electron microscopy, respectively. Electrorheological (ER) fluids were prepared by dispersing the PANI-CSA particles in silicone oil, and their steady-shear rheological properties under electric fields were investigated using a rotational rheometer with a high-voltage generator. The PANI-CSA synthesized in this study possesses typical ER behavior:shear stress increases with increasing electric field strengths.
引用
收藏
页码:823 / 827
页数:5
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