Light-Induced Increase of Electron Diffusion Length in a p-n Junction Type CH3NH3PbBr3 Perovskite Solar Cell

被引:91
作者
Kedem, Nir [1 ]
Brenner, Thomas M. [1 ]
Kulbak, Michael [1 ]
Schaefer, Norbert [2 ]
Levcenko, Sergiu [2 ]
Levine, Igal [1 ]
Abou-Ras, Daniel [2 ]
Hodes, Gary [1 ]
Cahen, David [1 ]
机构
[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel
[2] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-14109 Berlin, Germany
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2015年 / 6卷 / 13期
关键词
BEAM-INDUCED CURRENT; ARTIFICIAL PHOTOSYNTHESIS; VOLTAGE; MECHANISM; WATER; INTENSITY; EXCITONS; HYDROGEN;
D O I
10.1021/acs.jpclett.5b00889
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High band gap, high open-circuit voltage solar cells with methylammonium lead tribromide (MAPbBr(3)) perovskite absorbers are of interest for spectral splitting and photoelectrochemical applications, because of their good performance and ease of processing. The physical origin of high performance in these and similar perovskite-based devices remains only partially understood. Using cross-sectional electron-beam-induced current (EBIC) measurements, we find an increase in carrier diffusion length in MAPbBr(3)(Cl)-based solar cells upon low intensity (a few percent of 1 sun intensity) blue laser illumination. Comparing dark and illuminated conditions, the minority carrier (electron) diffusion length increases about 3.5 times from L-n = 100 +/- 50 nm to 360 +/- 22 nm. The EBIC cross section profile indicates a p-n structure between the n-FTO/TiO, and p-perovskite, rather than the p-i-n structure, reported for the iodide derivative. On the basis of the variation in space-charge region width with varying bias, measured by EBIC and capacitance-voltage measurements, we estimate the net-doping concentration in MAPbBr(3)(Cl) to be 3-6 x 10(17) cm(-3).
引用
收藏
页码:2469 / 2476
页数:8
相关论文
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