High-performance quenchometric oxygen sensors based on fluorinated xerogels doped with [Ru(dpp)3]2+

被引：126

作者：

Bukowski, RM

Ciriminna, R

Pagliaro, M

Bright, FV

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[2] CNR, Ist Studio Mat Nanostrutt, I-90146 Palermo, Italy

来源：

ANALYTICAL CHEMISTRY | 2005年 / 77卷 / 08期

关键词：

D O I：

10.1021/ac048199b

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

By using hybrid xerogels that are composed of alkyl and perfluoroalkyl ORMOSILs (organically modified silicates) doped with the luminophore tris(4,7'-diphenyl-1,10'-phenanthroline) ruthenium(II), we have produced highly sensitive O-2 sensors (i.e., I-N2/I-O2 = 35 +/- 4) with linear calibration curves that exhibit less than 2% drift over 6 months.

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收藏

页码：2670 / 2672

页数：3

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