Precision synthesis of organic/inorganic hybrid nanocapsules with a silanol-functionalized micelle template

被引：53

作者：

Koh, K ^{[1
]}

Ohno, K ^{[1
]}

Tsujii, Y ^{[1
]}

Fukuda, T ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 35期

关键词：

block copolymers; micelles; nanostructures; self-assembly; silicates;

D O I：

10.1002/anie.200351398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a nutshell: An amphiphilic block copolymer that bears protected silanol groups was synthesized by atom-transfer radical polymerization, and the amphiphile was assembled to form a micelle in an aqueous medium. The micelle was mixed with a solution of active silicate, which resulted in the formation of a silica layer on the micelle surface to produce a novel type of organic/inorganic hybrid nanocapsule (see scheme).

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收藏

页码：4194 / 4197

页数：4

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