AgOTf-promoted conversion of 4,5-epoxy-1-bromide into tetrahydropyran ring

被引：13

作者：

Hayashi, N ^{[1
]}

Fujiwara, K ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV, DIV CHEM, GRAD SCH SCI, SAPPORO, HOKKAIDO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 05期

关键词：

D O I：

10.1246/cl.1996.341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-1-Bromo-8-t-butyldiphenylsiloxy-4,5-epoxyoctane was treated with AgOTf in THF/H2O (5:1) to give trans-3-hydroxytetrahydropyran derivative as the major product (72%) by the expansion of the oxirane ring.

引用

页码：341 / 342

页数：2

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