Preparation and characterisation of C(70)Ph(9)OH; The first fullerene with a single hydroxy group attached to the cage

被引：29

作者：

Birkett, PR

Avent, AG

Darwish, AD

Kroto, HW

Taylor, R

Walton, DRM

机构：

[1] Sch. of Chem. and Molecular Sciences, University of Sussex, Brighton

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fullerenol C(70)Ph(9)OH is obtained as a minor product from the reaction of C70Cl10 with benzene/FeCl3 and is chiral due to the attachment of a hydroxy group and a phenyl group across the 7,8-bond; this adjacency inhibits free rotation of the 8-phenyl group.

引用

页码：1231 / 1232

页数：2

共 5 条

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AVENT, AG
BIRKETT, PR
CRANE, JD
DARWISH, AD
LANGLEY, GJ
KROTO, HW
TAYLOR, R
WALTON, DRM
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[2] HOLEY FULLERENES - A BIS-LACTONE DERIVATIVE OF [70]FULLERENE WITH AN 11-ATOM ORIFICE
BIRKETT, PR
AVENT, AG
DARWISH, AD
KROTO, HW
TAYLOR, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (18) : 1869 - 1870
[3] FORMATION AND CHARACTERIZATION OF C70CL10
BIRKETT, PR
AVENT, AG
DARWISH, AD
KROTO, HW
TAYLOR, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) : 683 - 684
[4] BIRKETT PR, 1996, TETRAHEDRON, V52, P5235
[5] CHIANG LY, 1995, CHEM FULLERENES, pCH5

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