HOLEY FULLERENES - A BIS-LACTONE DERIVATIVE OF [70]FULLERENE WITH AN 11-ATOM ORIFICE

被引:64
作者
BIRKETT, PR
AVENT, AG
DARWISH, AD
KROTO, HW
TAYLOR, R
WALTON, DRM
机构
关键词
D O I
10.1039/c39950001869
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C(70)Ph(8) spontaneously oxidises in air to form a bis-lactone C(70)Ph(8)O(4), having an eleven-membered hole in the fullerene cage; the reaction is believed to proceed via insertion of oxygen into 5,6 bonds followed by oxidative cleavage of the adjacent double bond, a process which has a precedent in the spontaneous oxidation of vinyl ethers to esters.
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页码:1869 / 1870
页数:2
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