Chemistry of biologically important synthetic organoselenium compounds

被引:1586
作者
Mugesh, G
du Mont, WW
Sies, H
机构
[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
[2] Univ Dusseldorf, Inst Physiol Chem 1, D-40001 Dusseldorf, Germany
关键词
D O I
10.1021/cr000426w
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemistry of biologically important synthetic organoselenium compounds was discussed. The x-ray crystal structure of the alkylating organoselenone ethyl phenyl selenone was also studied. It was found that the phosphoalkyl derivative of ebselen exhibited Se···O interactions which diminished the electrostatic charge on the selenium atoms. The analysis showed that the redox properties of selenium were influential in the catalytic activities of organoselenium compounds.
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页码:2125 / 2179
页数:55
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