AgI nanoplates with mesoscopic superionic conductivity at room temperature

被引：74

作者：

Guo, YG ^{[1
]}

Lee, JS ^{[1
]}

Maier, J ^{[1
]}

机构：

[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 23期

关键词：

D O I：

10.1002/adma.200501215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AgI nanoplates with unusual 7H and 9R polytype phases (see Figure) have been prepared in large quantities by a solution-based method using polyelectrolytes. The nanoplates exhibit extremely high conductivity, which is enhanced by four orders of magnitude compared to the macroscopic AgI phase (beta-AgI), and a surprising conductivity isotropy, both of which can be explained by mesoscopic ionic-conductivity effects in polytype heterostructures.

引用

页码：2815 / +

页数：6