Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry

被引：435

作者：

Beldon, Patrick J. ^{[1
]}

Fabian, Laszlo ^{[2
]}

Stein, Robin S. ^{[3
]}

Thirumurugan, A. ^{[4
]}

Cheetham, Anthony K. ^{[4
]}

Friscic, Tomislav ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Coll Cork, Dept Chem, Cork, Ireland

[3] Bruker UK Ltd, Coventry CV4 9GH, W Midlands, England

[4] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 50期

关键词：

grinding; imidazoles; mechanosynthesis; metal-organic frameworks; zeolite analogues; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; STEPWISE MECHANISM; EXTERNAL SURFACE; REACTIVITY; COCRYSTAL; NETWORKS; POLYMERS;

D O I：

10.1002/anie.201005547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Freshly ground: Improved mechanochemical methodologies, such as liquid-assisted grinding and ion- and liquid-assisted grinding enable the rapid and topologically selective synthesis of porous and nonporous zeolitic imidazolate frameworks with diverse topologies, at room temperature and directly from zinc oxide (see scheme). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9640 / 9643

页数：4