Mesoporous Metal-Organic Frameworks with Size-tunable Cages: Selective CO2 Uptake, Encapsulation of Ln3+ Cations for Luminescence, and Column-Chromatographic Dye Separation

被引：318

作者：

Lan, Ya-Qian ^{[1
,2
]}

Jiang, Hai-Long ^{[1
]}

Li, Shun-Li ^{[2
]}

Xu, Qiang ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 43期

关键词：

CARBON-DIOXIDE; HYDROGEN STORAGE; SURFACE-AREA; PORE-SIZE; ADSORPTION; CATALYSIS; CAPTURE; METHANE; TETRACARBOXYLATE; POROSITY;

D O I：

10.1002/adma.201102880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three mesoporous metal-organic frameworks (MOFs) with rare corundum-type topology and size-tailored cages are constructed by length-extendable tetratopic ligands. All the MOFs show selective CO 2 uptake over N 2 and their CO 2 uptake capabilities are discriminated with different cage sizes. The MOFs can serve as hosts for encapsulating extra-framework lanthanide cations, and be applicable in column-chromatographic separation for large dye molecules. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5015 / 5020

页数：6

共 60 条

[21] Ultrahigh Porosity in Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Ko, Nakeun ;

Go, Yong Bok ;

Aratani, Naoki ;

Choi, Sang Beom ;

Choi, Eunwoo ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. ;

O'Keeffe, Michael ;

Kim, Jaheon ;

Yaghi, Omar M. .

SCIENCE, 2010, 329 (5990) :424-428

[22] A highly porous flexible Metal-Organic Framework with corundum topology [J].

Gruenker, Ronny ;

Senkovska, Irena ;

Biedermann, Ralf ;

Klein, Nicole ;

Lohe, Martin R. ;

Mueller, Philipp ;

Kaskel, Stefan .

CHEMICAL COMMUNICATIONS, 2011, 47 (01) :490-492

[23] Gated Channels in a Honeycomb-like Zinc-Dicarboxylate-Bipyridine Framework with Flexible Alkyl Ether Side Chains [J].

Henke, Sebastian ;

Fischer, Roland A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (07) :2064-2067

[24] High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons [J].

Himeno, S ;

Komatsu, T ;

Fujita, S .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (02) :369-376

[25] Porous metal-organic frameworks as platforms for functional applications [J].

Jiang, Hai-Long ;

Xu, Qiang .

CHEMICAL COMMUNICATIONS, 2011, 47 (12) :3351-3370

[26] Non-, Micro-, and Mesoporous Metal-Organic Framework Isomers: Reversible Transformation, Fluorescence Sensing, and Large Molecule Separation [J].

Jiang, Hai-Long ;

Tatsu, Yoshiro ;

Lu, Zhang-Hui ;

Xu, Qiang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5586-+

[27] Crown-Ether-Like PbII-Metal Framework with Dual- and Bimodal Emissive Properties Based on Its Photochromic Precursor by Leaching [J].

Jiang, You-Yun ;

Ren, Shu-Kui ;

Ma, Jian-Ping ;

Liu, Qi-Kui ;

Dong, Yu-Bin .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (41) :10742-10746

[28] METAL-ORGANIC FRAMEWORKS Transported into fuel cells [J].

Kitagawa, Hiroshi .

NATURE CHEMISTRY, 2009, 1 (09) :689-690

[29] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[30] A Mesoporous Metal-Organic Framework [J].

Klein, Nicole ;

Senkovska, Irena ;

Gedrich, Kristina ;

Stoeck, Ulrich ;

Henschel, Antje ;

Mueller, Uwe ;

Kaskel, Stefan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9954-9957

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