Sum-frequency generation in chiral liquids near electronic resonance

被引：115

作者：

Belkin, MA

Han, SH

Wei, X

Shen, YR ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

来源：

PHYSICAL REVIEW LETTERS | 2001年 / 87卷 / 11期

关键词：

D O I：

10.1103/PhysRevLett.87.113001

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We demonstrate experimentally that visible-visible sum-frequency generation in the bulk of a chiral liquid is observable near electronic resonant transitions. Although the process is electric dipole allowed. it is rather weak because the orientational average over molecules effectively reduces the bulk chiral nonlinearity.

引用

收藏

页码：113001 / 113001

页数：4

相关论文

共 12 条

[1]

[Anonymous], 1994, P INT SCH PHYS

[2] Sum-frequency vibrational spectroscopy on chiral liquids: A novel technique to probe molecular chirality [J].

Belkin, MA ;

Kulakov, TA ;

Ernst, KH ;

Yan, L ;

Shen, YR .

PHYSICAL REVIEW LETTERS, 2000, 85 (21) :4474-4477

[3] 2ND-HARMONIC GENERATION CIRCULAR-DICHROISM SPECTROSCOPY FROM CHIRAL MONOLAYERS [J].

BYERS, JD ;

YEE, HI ;

PETRALLIMALLOW, T ;

HICKS, JM .

PHYSICAL REVIEW B, 1994, 49 (20) :14643-14647

[4] ELECTRONIC SPECTRAL EFFECTS ON CHIRAL SURFACE 2ND-HARMONIC GENERATION [J].

BYERS, JD ;

HICKS, JM .

CHEMICAL PHYSICS LETTERS, 1994, 231 (2-3) :216-224

[5] Three-wave mixing in chiral liquids [J].

Fischer, P ;

Wiersma, DS ;

Righini, R ;

Champagne, B ;

Buckingham, AD .

PHYSICAL REVIEW LETTERS, 2000, 85 (20) :4253-4256

[6]

GIORDMAINE JA, 1965, PHYS REV, V138, P1599

[7] BULK CONTRIBUTION IN SURFACE 2ND-HARMONIC GENERATION [J].

GUYOTSIONNEST, P ;

SHEN, YR .

PHYSICAL REVIEW B, 1988, 38 (12) :7985-7989

[8] CIRCULAR-DICHROISM SPECTROSCOPY AT INTERFACES - A SURFACE 2ND HARMONIC-GENERATION STUDY [J].

PETRALLIMALLOW, T ;

WONG, TM ;

BYERS, JD ;

YEE, HI ;

HICKS, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (07) :1383-1388

[9] COHERENT OPTICAL MIXING IN OPTICALLY ACTIVE LIQUIDS [J].

RENTZEPI.PM ;

GIORDMAI.JA ;

WECHT, KW .

PHYSICAL REVIEW LETTERS, 1966, 16 (18) :792-&

[10]

SHEN YR, 1984, PRINCIPLES NONLINEAR, pCH2