Translation and rotation of a haloaromatic thiol

被引：8

作者：

Bartels, L ^{[1
]}

Rao, BV ^{[1
]}

Liu, AW ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 385卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.cplett.2003.12.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lateral manipulation of a halosubstituted aromatic thiol (p-bromothiophenol) by use of a scanning tunneling microscope (STM) operated at cryogenic temperatures is always associated with the alignment of the molecule in the translation direction. Tip-height traces acquired during lateral manipulation yield further insight into the dynamic behavior of the molecule. CO-functionalization of the STM tip renders imaging conditions more stable by reducing the attractive interaction between the tip and the thiol. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：36 / 39

页数：4

共 18 条

[1] Basic steps of lateral manipulation of single atoms and diatomic clusters with a scanning tunneling microscope tip [J].

Bartels, L ;

Meyer, G ;

Rieder, KH .

PHYSICAL REVIEW LETTERS, 1997, 79 (04) :697-700

[2] Controlled vertical manipulation of single CO molecules with the scanning tunneling microscope: A route to chemical contrast [J].

Bartels, L ;

Meyer, G ;

Rieder, KH .

APPLIED PHYSICS LETTERS, 1997, 71 (02) :213-215

[3] MANIPULATION OF C-60 MOLECULES ON A SI SURFACE [J].

BETON, PH ;

DUNN, AW ;

MORIARTY, P .

APPLIED PHYSICS LETTERS, 1995, 67 (08) :1075-1077

[4]

Böhringer M, 1999, ANGEW CHEM INT EDIT, V38, P821, DOI 10.1002/(SICI)1521-3773(19990315)38:6<821::AID-ANIE821>3.0.CO

[5]

2-A

[6] Molecular-based electronically switchable tunnel junction devices [J].

Collier, CP ;

Jeppesen, JO ;

Luo, Y ;

Perkins, J ;

Wong, EW ;

Heath, JR ;

Stoddart, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (50) :12632-12641

[7] IMAGING STANDING WAVES IN A 2-DIMENSIONAL ELECTRON-GAS [J].

CROMMIE, MF ;

LUTZ, CP ;

EIGLER, DM .

NATURE, 1993, 363 (6429) :524-527

[8] POSITIONING SINGLE ATOMS WITH A SCANNING TUNNELING MICROSCOPE [J].

EIGLER, DM ;

SCHWEIZER, EK .

NATURE, 1990, 344 (6266) :524-526

[9] Molecule cascades [J].

Heinrich, AJ ;

Lutz, CP ;

Gupta, JA ;

Eigler, DM .

SCIENCE, 2002, 298 (5597) :1381-1387

[10] Inducing all steps of a chemical reaction with the scanning tunneling microscope tip: Towards single molecule engineering [J].

Hla, SW ;

Bartels, L ;

Meyer, G ;

Rieder, KH .

PHYSICAL REVIEW LETTERS, 2000, 85 (13) :2777-2780

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