Synthesis and structure of the octanuclear manganese(II) cage [(η-Cp)Mn{2-NH(4,6-Me2pm)•Mn{2-N(4,6-Me2Pm)}]4 (Cp = C5H5, pm = pyrimidine)

被引：17

作者：

Aluarez, CS ^{[1
]}

Bond, AD ^{[1
]}

Harron, EA ^{[1
]}

Layfield, RA ^{[1
]}

McAllister, JA ^{[1
]}

Pask, CM ^{[1
]}

Rawson, JM ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 20期

关键词：

D O I：

10.1021/om010357r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1:1 reaction of 2-NH2(4,6-Me(2)pm) with Cp2Mn in thf gives the novel heteroleptic imido / amido, Mn(II) cage [(eta -Cp)Mn{2-NH(4,6-Me(2)pm)}. Mn{2-N(4,6-Me(2)pm)}](4) (1), composed of a central Mn(II) imido, [Mn-4{2-N(4,6-Me(2)pm)}(4)] core coordinated at the periphery by four [(eta -Cp)Mn{2-NH(4,6-Me(2)pm)}] monomer units.

引用

页码：4135 / 4137

页数：3

共 26 条

[1] Manganese carboxylate clusters: from structural aesthetics to single-molecule magnets [J].

Aromi, G ;

Aubin, SMJ ;

Bolcar, MA ;

Christou, G ;

Eppley, HJ ;

Folting, K ;

Hendrickson, DN ;

Huffman, JC ;

Squire, RC ;

Tsai, HL ;

Wang, S ;

Wemple, MW .

POLYHEDRON, 1998, 17 (17) :3005-3020

[2] SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE METAL BORYLAMIDE COMPLEXES LI(ET2O)2NPHBMES2, (THF)(ET2O)2LICLCO(NPHBMES2)2, AND MN(NMESBMES2)2.3PHME (MES = 2,4,6-ME3C6H2) - MODIFIED AMIDE LIGANDS WITH POOR BRIDGING AND PI-DONOR CHARACTERISTICS [J].

BARTLETT, RA ;

FENG, XD ;

OLMSTEAD, MM ;

POWER, PP ;

WEESE, KJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :4851-4854

[3] The paramagnetic, heterometallic manganese cubanes [{E2(NCy)4}(MnCp)2] (Cy = C6H11, Cp = C5H5, E = As, Sb) [J].

Bashall, A ;

Beswick, MA ;

Ehlenberg, H ;

Kidd, SJ ;

McPartlin, M ;

Palmer, JS ;

Raithby, PR ;

Rawson, JM ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 2000, (09) :749-750

[4] SYNTHESIS AND REACTIVITY OF MANGANESE(II) DIALKYLAMIDO COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF (MN3(MU-NET2)6-(MU-CL)2(LI(THF)2)2).C7H16 (THF = TETRAHYDROFURAN) AND (MN2(MU-NPRI2)2(NPRI2)2) [J].

BELFORTE, A ;

CALDERAZZO, F ;

ENGLERT, U ;

STRAHLE, J ;

WURST, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (09) :2419-2427

[5] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE 1ST MANGANESE(II) DIALKYLAMIDO COMPLEX - (MN3(MU-NET2)6(MU-CL)2[LI(THF)2]2).(C7H16) (THF = TETRAHYDROFURAN) [J].

BELFORTE, A ;

CALDERAZZO, F ;

ENGLERT, U ;

STRAHLE, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (12) :801-802

[6] CRYSTAL STRUCTURE OF CYCLOPENTADIENYL MANGANESE TRICARBONYL, C5H5MN(CO)3 [J].

BERNDT, AF ;

MARSH, RE .

ACTA CRYSTALLOGRAPHICA, 1963, 16 (02) :118-&

[7] Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [(Ph(3)P)(2)CuL(2)Li(thf)(2)]center dot thf and tetrameric [{CuL(PPh(3))}(4)] (L=1,3-benzoxazoline-2-thionate, thf equals tetrahydrofuran) [J].

Beswick, MA ;

Brasse, C ;

Halcrow, MA ;

Raithby, PR ;

Russell, CA ;

Steiner, A ;

Snaith, R ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (19) :3793-3797

[8]

Beswick MA, 1998, CHEM SOC REV, V27, P225

[9] Nucleophilic substitution vs acid-base reactions of [Mn{N(SiMe3)(2)}(2)]center dot 2thf; Syntheses and structures of 2[Li(thf)(4)](+)[Mn(C12H8H)(4)](2-)center dot C6H5Me and [Mn(C12H8N)(2)]center dot 3thf (thf equals tetrahydrofuran, C12H8N equals carbazol-9-yl) [J].

Beswick, MA ;

Harmer, CN ;

Raithby, PR ;

Steiner, A ;

Verhorevoort, KL ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (12) :2029-2032

[10] The hydrogen bonded polymer structures of [{Mn(2-mbiH)2•TMEDA}•A-A]∞ [2-mbiH2=2-mercaptobenzimidazole;: A-A = TMEDA (Me2NCH2CH2NMe2) or DABCO (N{CH2CH2}3N)] [J].

Beswick, MA ;

Mosquera, MEG ;

Palmer, JS ;

Raithby, PR ;

Wright, DS .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (10) :1033-1039

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