Chiral teleinduction in the formation of a macromolecular multistate chiroptical redox switch

被引：73

作者：

Gomar-Nadal, E ^{[1
]}

Veciana, J ^{[1
]}

Rovira, C ^{[1
]}

Amabilino, DB ^{[1
]}

机构：

[1] CSIC, Inst Ciencia Mat Barcelona, Dept Nanociencia Mol & Mat Organ, ES-08193 Bellaterra, Catalonia, Spain

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 17期

关键词：

D O I：

10.1002/adma.200500348

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A multistate chiroptical macromoleular switch based on the redox behavior of tetrathiafulvalene (TTF) units has been prepared from a chiral TTF functionalized with an isocyanide group. Polymerization takes place diastereo-selectively due to an unusually long-range chiral induction, yielding a helical backbone with organized electroactive side groups (see Figure). This organized redox system may lead to applications in molecular devices.

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页码：2095 / +

页数：5

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