Nanowindow-regulated specific capacitance of supercapacitor electrodes of single-wall carbon nanohorns

被引：271

作者：

Yang, Cheol-Min

Kim, Yong-Jung

Endo, Morinobu

Kanoh, Hirofumi

Yudasaka, Masako

Iijima, Sumio

Kaneko, Katsumi

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Inage, Chiba 2638522, Japan

[2] Shinshu Univ, Inst Carbon Sci & Technol, Nagano 3808553, Japan

[3] NEC Corp Ltd, SORST, Japan Sci & Technol Agcy, Tsukuba, Ibaraki 3058501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 01期

关键词：

D O I：

10.1021/ja065501k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvated ion size of electrolytes increases in the following order; SO42-(H2O)12 (0.53 nm) < (C2H5)4N+·7acetonitrile (Et4N+·7ACN, 1.30 nm) < (C2H5)4N+·4propylene carbonate (Et4N+·4PC, 1.35 nm). The size difference between the nanowindows of single-wall carbon nanohorns and the solvated ions of electrolytes should be an important factor in the accessibility of the ions to the internal spaces through the nanowindow. Copyright © 2006 American Chemical Society.

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页码：20 / 21

页数：2

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