Aminooxycarbene behavior of a carbamoylsilane

被引：20

作者：

Cunico, RF ^{[1
]}

机构：

[1] No Illinois Univ, Dept Biochem & Chem, De Kalb, IL 60115 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 16期

关键词：

carbamoylsilane; siloxyaminocarbene; carbamoylsilylation;

D O I：

10.1016/S0040-4039(01)00336-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A carbamoylsilane behaves as a siloxyaminocarbene towards electrophilic reagents, undergoing C-H insertion with chloroform, methyl propiolate and 1-chloro-2,4-dinitrobenzene. Its reaction with DMAD results in carbamoylsilylation. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：2931 / 2932

页数：2

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