Synthesis of aminophenyl and methoxyphenyl perfluoroalkyl ketones

被引：10

作者：

Lee, HR

Czarny, A

Battiste, MA

Strekowski, L ^{[1
]}

机构：

[1] Georgia State Univ, Dept Chem, Atlanta, GA 30303 USA

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 91卷 / 02期

关键词：

perfluoroalkyl anilines; perfluoroalkyl anisoles; perfluoroalkyl acetals; hydrolysis;

D O I：

10.1016/S0022-1139(98)00230-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds are obtained by direct hydrolysis of the corresponding 2/4-perfluoroalkyl-substituted anilines and anisoles by the system AcOH/HBr/H2O/Al2O3. A two-step preparation of 2/4-perfluoroacylanilines involves the treatment of the 2/4-perfluoroalkylaniline with sodium ethoxide followed by hydrolysis of the resultant diethyl acetal with hydriodic acid. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：221 / 224

页数：4

共 13 条

[11] REACTIONS OF TRIFLUOROMETHYL BROMIDE AND RELATED HALIDES .10. PERFLUOROALKYLATION OF AROMATIC-COMPOUNDS INDUCED BY SULFUR-DIOXIDE RADICAL-ANION PRECURSORS [J].