Fused polycyclic nucleophilic carbenes - synthesis, structure, and function

被引：96

作者：

Arduengo, Anthony J., III ^{[1
]}

Iconaru, Luigi I. ^{[1
]}

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

DALTON TRANSACTIONS | 2009年 / 35期

基金：

美国国家科学基金会;

关键词：

N-HETEROCYCLIC CARBENE; TRANSITION-METAL-COMPLEXES; OLEFIN-METATHESIS CATALYSTS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; CROSS-COUPLING REACTIONS; DIELS-ALDER REACTIONS; BETA-LACTAM FORMATION; STEREOSELECTIVE-SYNTHESIS; GAMMA-BUTYROLACTONES; ASYMMETRIC-SYNTHESIS;

D O I：

10.1039/b907211j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interest in stable nucleophilic carbenes has grown rapidly since the isolation of the first "bottle-able" example in 1991. Not only has the structural variation of this class of compounds seen an incredible expansion from laboratories around the world, but the chemical reactivity of these compounds has opened many new opportunities for improvements in chemical transformations and invention of new processes. This article reflects our particular interest in fused polycyclic carbenes and focuses on this broad chemical class from both a structural and reactivity perspective.

引用

页码：6903 / 6914

页数：12

共 179 条

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