Fully Printed Halide Perovskite Light-Emitting Diodes with Silver Nanowire Electrodes

被引：251

作者：

Bade, Sri Ganesh R. ^{[1
]}

Li, Junqiang ^{[1
]}

Shan, Xin ^{[1
]}

Ling, Yichuan ^{[5
]}

Tian, Yu ^{[7
]}

Dilbeck, Tristan ^{[6
]}

Besara, Tiglet ^{[3
]}

Geske, Thomas ^{[1
,7
]}

Gao, Hanwei ^{[5
,7
]}

Ma, Biwu ^{[2
,6
,7
]}

Hanson, Kenneth ^{[6
,7
]}

Siegrist, Theo ^{[2
,3
,7
]}

Xu, Chengying ^{[4
]}

Yu, Zhibin ^{[1
,6
,7
]}

机构：

[1] Florida State Univ, High Performance Mat Inst, Dept Ind & Mfg Engn, Tallahassee, FL 32310 USA

[2] Florida State Univ, Dept Chem & Biomed Engn, Tallahassee, FL 32310 USA

[3] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

[4] Florida State Univ, Dept Mech Engn, Tallahassee, FL 32310 USA

[5] Florida State Univ, Dept Phys, Tallahassee, FL 32306 USA

[6] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[7] Florida State Univ, Mat Sci & Engn, Tallahassee, FL 32306 USA

来源：

ACS NANO | 2016年 / 10卷 / 02期

基金：

美国国家科学基金会;

关键词：

halide perovskites; printed electronics; light-emitting diodes; composites; flexible electronics; moisture; SOLAR-CELLS; INTERFACIAL CONTROL; THIN-FILMS; EFFICIENT; MOISTURE; PERFORMANCE; DEVICES; STABILITY; LAYER; STATE;

D O I：

10.1021/acsnano.5b07506

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Printed organometal halide perovskite light-emitting diodes (LEDs) are reported that have indium tin oxide (ITO) or carbon nanotubes (CNTs) as the transparent anode, a printed composite film consisting of methylammonium lead tribromide (Br-Pero) and poly(ethylene oxide) (PEO) as the emissive layer, and printed silver nanowires as the cathode. The fabrication can be carried out in ambient air without humidity control. The devices on ITO/glass have a low turn-on voltage of 2.6 V, a maximum luminance intensity of 21014 cd m(-2), and a maximum external quantum efficiency (EQE) of 1.1%, surpassing previous reported perovskite LEDs. The devices on CNTs/polymer were able to be strained to 5 mm radius of curvature without affecting device properties.

引用

页码：1795 / 1801

页数：7

共 31 条

[1] Light-Emitting Electrochemical Cells Based on Hybrid Lead Halide Perovskite Nanoparticles [J].

Aygueler, Meltem F. ;

Weber, Michael D. ;

Puscher, Bianka M. D. ;

Medina, Dana D. ;

Docampo, Pablo ;

Costa, Ruben D. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (21) :12047-12054

[2] High-efficiency tandem perovskite solar cells [J].

Bailie, Colin D. ;

McGehee, Michael D. .

MRS BULLETIN, 2015, 40 (08) :681-685

[3] Influence of moisture on the preparation, crystal structure, and photophysical properties of organohalide perovskites [J].

Bass, Kelsey K. ;

McAnally, R. Eric ;

Zhou, Shiliang ;

Djurovich, Peter I. ;

Thompson, Mark E. ;

Melot, Brent C. .

CHEMICAL COMMUNICATIONS, 2014, 50 (99) :15819-15822

[4] Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air [J].

Christians, Jeffrey A. ;

Miranda Herrera, Pierre A. ;

Kamat, Prashant V. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (04) :1530-1538

[5] The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication [J].

Eperon, Giles E. ;

Habisreutinger, Severin N. ;

Leijtens, Tomas ;

Bruijnaers, Bardo J. ;

van Franeker, Jacobus J. ;

dequilettes, Dane W. ;

Pathak, Sandeep ;

Sutton, Rebecca J. ;

Grancini, Giulia ;

Ginger, David S. ;

Janssen, Rene A. J. ;

Petrozza, Annamaria ;

Snaith, Henry J. .

ACS NANO, 2015, 9 (09) :9380-9393

[6] Efficient photovoltaic and electroluminescent perovskite devices [J].

Gil-Escrig, Lidon ;

Longo, Giulia ;

Pertegas, Antonio ;

Roldan-Carmona, Cristina ;

Soriano, A. ;

Sessolo, Michele ;

Bolink, Henk J. .

CHEMICAL COMMUNICATIONS, 2015, 51 (03) :569-571

[7] Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al2O3 Buffer Layer [J].

Guarnera, Simone ;

Abate, Antonio ;

Zhang, Wei ;

Foster, Jamie M. ;

Richardson, Giles ;

Petrozza, Annamaria ;

Snaith, Henry J. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (03) :432-437

[8] Enhanced Performance in Fluorene-Free Organometal Halide Perovskite Light-Emitting Diodes using Tunable, Low Electron Affinity Oxide Electron Injectors [J].

Hoye, Robert L. Z. ;

Chua, Matthew R. ;

Musselman, Kevin P. ;

Li, Guangru ;

Lai, May-Ling ;

Tan, Zhi-Kuang ;

Greenham, Neil C. ;

MacManus-Driscoll, Judith L. ;

Friend, Richard H. ;

Credgington, Dan .

ADVANCED MATERIALS, 2015, 27 (08) :1414-+

[9] Enhancing Stability of Perovskite Solar Cells to Moisture by the Facile Hydrophobic Passivation [J].

Hwang, Insung ;

Jeong, Inyoung ;

Lee, Jinwoo ;

Ko, Min Jae ;

Yong, Kijung .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (31) :17330-17336

[10] Toward Large Scale Roll-to-Roll Production of Fully Printed Perovskite Solar Cells [J].

Hwang, Kyeongil ;

Jung, Yen-Sook ;

Heo, Youn-Jung ;

Scholes, Fiona H. ;

Watkins, Scott E. ;

Subbiah, Jegadesan ;

Jones, David J. ;

Kim, Dong-Yu ;

Vak, Doojin .

ADVANCED MATERIALS, 2015, 27 (07) :1241-1247

← 1 2 3 4 →