Crystal-Plane-Controlled Surface Restructuring and Catalytic Performance of Oxide Nanocrystals

被引：150

作者：

Bao, Huizhi ^{[1
,2
]}

Zhang, Wenhua ^{[3
]}

Hua, Qing ^{[1
,2
]}

Jiang, Zhiquan ^{[1
,2
]}

Yang, Jinlong ^{[1
,2
]}

Huang, Weixin ^{[1
,2
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China

[3] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

基金：

中国国家自然科学基金;

关键词：

Cu2O nanocrystals; nanocatalysis; oxidation; structure-activity relationships; surface chemistry; SHAPE CHANGES; CO OXIDATION; IN-SITU; RECONSTRUCTION; REACTIVITY; MECHANISM;

D O I：

10.1002/anie.201103698

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal clear: Uniform Cu 2O nanooctahedra (o-Cu 2O) and nanocubes (c-Cu 2O) undergo surface restructuring during CO oxidation for the in-situ formation of catalytically active CuO thin films to give CuO/o-Cu 2O and CuO/c-Cu 2O, respectively (see picture). The structure and catalytic performance of CuO thin films are controlled by the crystal plane exposed on the underlying Cu 2O nanocrystals. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12294 / 12298

页数：5

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