Novel silver(I)-organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions

被引：148

作者：

Pan, L

Woodlock, EB

Wang, XT

Lam, KC

Rheingold, AL

机构：

[1] Univ Colorado, Dept Chem, Denver, CO 80217 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b104074j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structurally distinct coordination polymers [Ag(bpp)]ClO4 1 and [Ag(bpp)]PF6 2 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion of 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)-organic coordination polymers.

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页码：1762 / 1763

页数：2

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