Synthesis and spectrokinetic studies of spiro[thioxanthene-naphthopyrans]

被引：41

作者：

Coelho, PJ ^{[1
]}

Carvalho, LM

Abrantes, S

Oliveira, MM

Oliveira-Campos, AMF

Samat, A

Guglielmetti, R

机构：

[1] Univ Tras os Montes & Alto Douro, Dept Quim, P-5001911 Vila Real, Portugal

[2] Univ Minho, Ctr Quim, IBQF, P-4710 Braga, Portugal

[3] Univ Mediterranee, LCMOM, UMR 6114, CNRS, F-13288 Marseille 9, France

来源：

TETRAHEDRON | 2002年 / 58卷 / 47期

关键词：

photochromism; spiro[thioxanthene-naphthopyrans; naphthopyrans; heterocycles; spectrokinetics;

D O I：

10.1016/S0040-4020(02)01278-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several new spiro[thioxanthene-naphthopyrans] were prepared from substituted naphthols using a one step reaction. The photochromic properties of the new compounds were studied under flash photolysis and continuous irradiation. Compared to reference compounds general significant bathochromic shifts in the absorption spectra of the open forms, faster thermal bleaching kinetics and interesting fatigue resistances were observed. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：9505 / 9511

页数：9