Fullerene imposed high open-circuit voltage in efficient perovskite based solar cells

被引:49
作者
Gil-Escrig, Lidon [1 ]
Momblona, Cristina [1 ]
Sessolo, Michele [1 ]
Bolink, Henk J. [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, C Catedratico J Beltran 2, Paterna 46980, Spain
基金
欧盟地平线“2020”;
关键词
D O I
10.1039/c5ta10574a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Five different commercially available fullerenes are evaluated as hole blocking/electron transporting materials in p-i-n methylammonium lead iodide perovskite solar cells using a vacuum deposited perovskite absorber layer. A significant enhancement of the solar cell performance can be obtained by selecting a suitable fullerene derivative. Open-circuit voltages as high as 1.11 volts are obtained leading to a power conversion efficiency of 14.6%.
引用
收藏
页码:3667 / 3672
页数:6
相关论文
共 36 条
[1]   Efficient and Uniform Planar-Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition [J].
Chen, Chang-Wen ;
Kang, Hao-Wei ;
Hsiao, Sheng-Yi ;
Yang, Po-Fan ;
Chiang, Kai-Ming ;
Lin, Hao-Wu .
ADVANCED MATERIALS, 2014, 26 (38) :6647-6652
[2]   Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].
Chen, Qi ;
Zhou, Huanping ;
Hong, Ziruo ;
Luo, Song ;
Duan, Hsin-Sheng ;
Wang, Hsin-Hua ;
Liu, Yongsheng ;
Li, Gang ;
Yang, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625
[3]   Planar heterojunction perovskite/PC71BM solar cells with enhanced open-circuit voltage via a (2/1)-step spin-coating process [J].
Chiang, Chien-Hung ;
Tseng, Zong-Liang ;
Wu, Chun-Guey .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (38) :15897-15903
[4]   Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach [J].
Conings, Bert ;
Baeten, Linny ;
De Dobbelaere, Christopher ;
D'Haen, Jan ;
Manca, Jean ;
Boyen, Hans-Gerd .
ADVANCED MATERIALS, 2014, 26 (13) :2041-2046
[5]   A photophysical study of PCBM thin films [J].
Cook, Steffan ;
Ohkita, Hideo ;
Kim, Youngkyoo ;
Benson-Smith, Jessica J. ;
Bradley, Donal D. C. ;
Durrant, James R. .
CHEMICAL PHYSICS LETTERS, 2007, 445 (4-6) :276-280
[6]   Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates [J].
Docampo, Pablo ;
Ball, James M. ;
Darwich, Mariam ;
Eperon, Giles E. ;
Snaith, Henry J. .
NATURE COMMUNICATIONS, 2013, 4
[7]   Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Docampo, Pablo ;
Goriely, Alain ;
Snaith, Henry J. .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :151-157
[8]   Efficient photovoltaic and electroluminescent perovskite devices [J].
Gil-Escrig, Lidon ;
Longo, Giulia ;
Pertegas, Antonio ;
Roldan-Carmona, Cristina ;
Soriano, A. ;
Sessolo, Michele ;
Bolink, Henk J. .
CHEMICAL COMMUNICATIONS, 2015, 51 (03) :569-571
[9]   Nickel Oxide Electrode Interlayer in CH3NH3PbI3 Perovskite/PCBM Planar-Heterojunction Hybrid Solar Cells [J].
Jeng, Jun-Yuan ;
Chen, Kuo-Cheng ;
Chiang, Tsung-Yu ;
Lin, Pei-Ying ;
Tsai, Tzung-Da ;
Chang, Yun-Chorng ;
Guo, Tzung-Fang ;
Chen, Peter ;
Wen, Ten-Chin ;
Hsu, Yao-Jane .
ADVANCED MATERIALS, 2014, 26 (24) :4107-4113
[10]   CH3NH3PbI3 Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells [J].
Jeng, Jun-Yuan ;
Chiang, Yi-Fang ;
Lee, Mu-Huan ;
Peng, Shin-Rung ;
Guo, Tzung-Fang ;
Chen, Peter ;
Wen, Ten-Chin .
ADVANCED MATERIALS, 2013, 25 (27) :3727-3732