Fullerene imposed high open-circuit voltage in efficient perovskite based solar cells

被引:49
作者
Gil-Escrig, Lidon [1 ]
Momblona, Cristina [1 ]
Sessolo, Michele [1 ]
Bolink, Henk J. [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, C Catedratico J Beltran 2, Paterna 46980, Spain
基金
欧盟地平线“2020”;
关键词
D O I
10.1039/c5ta10574a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Five different commercially available fullerenes are evaluated as hole blocking/electron transporting materials in p-i-n methylammonium lead iodide perovskite solar cells using a vacuum deposited perovskite absorber layer. A significant enhancement of the solar cell performance can be obtained by selecting a suitable fullerene derivative. Open-circuit voltages as high as 1.11 volts are obtained leading to a power conversion efficiency of 14.6%.
引用
收藏
页码:3667 / 3672
页数:6
相关论文
共 36 条
[11]   Multicolored Organic/Inorganic Hybrid Perovskite Light-Emitting Diodes [J].
Kim, Young-Hoon ;
Cho, Himchan ;
Heo, Jin Hyuck ;
Kim, Tae-Sik ;
Myoung, NoSoung ;
Lee, Chang-Lyoul ;
Im, Sang Hyuk ;
Lee, Tae-Woo .
ADVANCED MATERIALS, 2015, 27 (07) :1248-1254
[12]   Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells [J].
Kojima, Akihiro ;
Teshima, Kenjiro ;
Shirai, Yasuo ;
Miyasaka, Tsutomu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (17) :6050-+
[13]   Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites [J].
Lee, Michael M. ;
Teuscher, Joel ;
Miyasaka, Tsutomu ;
Murakami, Takurou N. ;
Snaith, Henry J. .
SCIENCE, 2012, 338 (6107) :643-647
[14]   Roles of Fullerene-Based Interlayers in Enhancing the Performance of Organometal Perovskite Thin-Film Solar Cells [J].
Liang, Po-Wei ;
Chueh, Chu-Chen ;
Williams, Spencer T. ;
Jen, Alex K. -Y. .
ADVANCED ENERGY MATERIALS, 2015, 5 (10)
[15]   Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells [J].
Liang, Po-Wei ;
Liao, Chien-Yi ;
Chueh, Chu-Chen ;
Zuo, Fan ;
Williams, Spencer T. ;
Xin, Xu-Kai ;
Lin, Jiangjen ;
Jen, Alex K. -Y. .
ADVANCED MATERIALS, 2014, 26 (22) :3748-3754
[16]  
Lin QQ, 2015, NAT PHOTONICS, V9, P106, DOI [10.1038/nphoton.2014.284, 10.1038/NPHOTON.2014.284]
[17]   Efficient planar heterojunction perovskite solar cells by vapour deposition [J].
Liu, Mingzhen ;
Johnston, Michael B. ;
Snaith, Henry J. .
NATURE, 2013, 501 (7467) :395-+
[18]   Metal-Oxide-Free Methylammonium Lead Iodide Perovskite-Based Solar Cells: the Influence of Organic Charge Transport Layers [J].
Malinkiewicz, Olga ;
Roldan-Carmona, Cristina ;
Soriano, Alejandra ;
Bandiello, Enrico ;
Camacho, Luis ;
Nazeeruddin, Mohammad Khaja ;
Bolink, Henk J. .
ADVANCED ENERGY MATERIALS, 2014, 4 (15)
[19]  
Malinkiewicz O, 2014, NAT PHOTONICS, V8, P128, DOI [10.1038/NPHOTON.2013.341, 10.1038/nphoton.2013.341]
[20]   Strong Internal and External Luminescence as Solar Cells Approach the Shockley-Queisser Limit [J].
Miller, Owen D. ;
Yablonovitch, Eli ;
Kurtz, Sarah R. .
IEEE JOURNAL OF PHOTOVOLTAICS, 2012, 2 (03) :303-311