The chemical synthesis of a cyclic oligosaccharide derivative with branching

被引：4

作者：

Kasuya, MC ^{[1
]}

Hatanaka, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

关键词：

glycosidation; polymerization; oligomer;

D O I：

10.1016/S0040-4039(98)02234-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cyclic oligosaccharide derivative was synthesized by cationic ring-opening polymerization of an anhydrodisaccharide derivative under high vacuum in dichloromethane with 20 mol% of PF5 as initiator. Analysis of the spectral results showed that the oligomer chain is composed of only 3 glucose units connected by alpha-1,6 linkages with a glucopyranosyl branching unit at C-4 of each sugar residue in the main chain. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9719 / 9722

页数：4

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