New efficient catalysts for the aerobic oxidation of ethers

被引：10

作者：

Romano, AM ^{[1
]}

Ricci, M ^{[1
]}

机构：

[1] IST GUIDO DONEGANI SPA,ENICHEM,I-28100 NOVARA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 120卷 / 1-3期

关键词：

aerobic oxidation; ethers; nickel; copper; silver;

D O I：

10.1016/S1381-1169(96)00418-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some nickel, copper, and silver salts or complexes are efficient catalysts for the oxidation of benzylic ethers with oxygen in 1,2-dimethoxyethane. Salts of the weakly coordinating anion trifluoroacetate are particularly efficient, approaching (and, in some cases, improving) the yields obtained with cobalt(II) chloride, the best catalyst so far reported.

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页码：71 / 74

页数：4

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