Oxo osmium(VIII) complexes in oxidation: crystal structures of OsO4 center dot nmo (nmo=N-methylmorpholine N-oxide) and OsO4 center dot nmm (nmm=N-methylmorpholine), and use of cis-[OsO4(OH)2](2-) as an oxidation catalyst

被引：23

作者：

Bailey, AJ

Bhowon, MG

Griffith, WP

Shoair, AGF

White, AJP

Williams, DJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,INORGAN CHEM LAB,LONDON SW7 2AY,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a702965i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complexes OsO4.nmo (nmo = N-methylmorpholine N-oxide) and OsO4.nmm (nmm = N,-methylmorpholine) have been made, their crystal structures determined, and their possible involvement in the catalysed dihydroxylation of alkenes considered. The use of cis-[OsO4(OH)(2)](2-) as a catalyst for the oxidation of alcohols, aldehydes and alkyl halides to carboxylic acids with [Fe(CN)(6)](3-) and other co-oxidants and also for the cleavage and dihydroxylation of alkenes with [Fe(CN)(6)](3-) has been investigated.

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页码：3245 / 3250

页数：6

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