Some key metabolic intermediates in the biosynthesis of botrydial and related compounds

被引：26

作者：

Durán-Patrón, R ^{[1
]}

Colmenares, AJ ^{[1
]}

Hernández-Galán, R ^{[1
]}

Collado, IG ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Puerto Real 11510, Cadiz, Spain

来源：

TETRAHEDRON | 2001年 / 57卷 / 10期

关键词：

Botrytis cinerea; metabolic intermediate; biosynthesis; probotryane; botrydial;

D O I：

10.1016/S0040-4020(01)00016-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The isolation of three key intermediates from a culture of Botrytis cinerea sheds further light on the biosynthetic pathway to botrydial (2), and clarifies and establishes the stereochemistry of the oxidative steps which affect the probotryane skeleton to lead to the dialdehyde (2). The structures of these three new metabolites have been determined by means of extensive spectroscopic methods. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1929 / 1933

页数：5

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