Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles

被引：130

作者：

Nishimura, T ^{[1
]}

Yoshinaka, T ^{[1
]}

Nishiguchi, Y ^{[1
]}

Maeda, Y ^{[1
]}

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6068510, Japan

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 12期

关键词：

D O I：

10.1021/ol0507120

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C-C bond fission at the sterically more hindered site.

引用

页码：2425 / 2427

页数：3

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